LA-ICP-MS硅酸盐矿物原位微区分析方法研究     

陈雪 《地质与勘探》2014,50(Z1):1413-1417

建立了一种利用New Wave UP 213 nm激光和ThermoFisher X Series2四极杆等离子体质谱法直接测定硅酸盐矿物中54种元素的分析方法。该方法以40Ca为内标、玻璃标准参考物质NIST SRM 610为外标,通过调节载气流量、激光频率、激光能量、激光剥蚀斑径降低元素分馏效应,并对NIST SRM 612进行测定,测定结果满足分析要求,54种元素的相对标准偏差大都低于10%,可应用于地质学分析研究。  相似文献   

Isotopic Composition of Dissolved Carbonates Meromictic Soda Lake Doroninskoe(Eastern Transbaikalia,Russia)   总被引：1，自引：0，他引：1  

Leonid V. ZAMANA  Svetlana V. BORZENKO 《《地质学报》英文版》2014,88(Z1):395-397

正1 Introduction Meromictic soda Lake Doroninskoe localized in the intermountain area,filled with continental sediments of the Mesozoic,in the upper basin of the river Amur.Coordinates of its location are N51°14'42"E112°14'40",  相似文献   

Trace metal composition of colloidal organic material in marine environments   总被引：2，自引：0，他引：2  

Laodong Guo  Peter H. Santschi  Kent W. Warnken 《Marine Chemistry》2000,70(4)

Marine colloidal material (1 kDa–0.2 μm) was isolated by cross-flow ultrafiltration followed by diafiltration and freeze-drying from surface waters of the Gulf of Mexico and the Middle Atlantic Bight (MAB), as well as from estuarine waters of Galveston Bay. Elemental characterization of isolated colloidal material included organic carbon (OC) and selected trace metal (Cu, Pb, Zn, Cd, Co, Ni, Cr, Be, Fe, Al, Mn, V, Ba, and Ti) determinations. It was found that levels of these metals in marine colloids ranged from <0.1 to 50 μg/g colloidal matter, except for Fe which generally had a concentration >120 μg/g. Most metals (Cu, Pb, Zn, Ni, Al, Mn, V, and Ti) had an average concentration >1 μg/g while concentrations of Cd, Co and Be were usually <1 μg/g. Metal concentrations (μg/g) in isolated colloids were, in general, higher in Galveston Bay than in the Gulf of Mexico, suggesting either high abundance of trace metals in estuarine waters or differences in organic matter composition. Higher colloidal metal concentrations in the MAB than in the Gulf of Mexico might be due to higher terrestrial inputs in the MAB. Colloidal metal concentrations (μg/g) were generally lower than those in average soils, continental crust and suspended particles. However, metal/aluminum ratios (Me/Al) in isolated marine colloids were significantly higher than those for average soils and continental crust. Most importantly, colloids had a metal composition and metal/OC ratio (Me/C) similar to humic substances and marine plankton, suggesting that marine colloids largely originate from planktonic sources and are composed of predominately organic components. The Me/C ratios of Galveston Bay colloids followed the sequence of Cu>Ni, Cr, Zn>Mn>Co>Pb, Cd, which is similar to the Irving–Williams order except for Mn, suggesting that the interaction of metals with marine colloids is determined by the affinity of metals for specific organic ligands.  相似文献   

环青海湖地下水溶解性碳的时空变化特征     

李东昇  崔步礼  赵云朵 《地理研究》2022,41(10):2821-2831

区域地下水溶解性碳的时空变化特征研究对于认识区域物质循环和能量传递及推动区域生态可持续发展具有重要意义。本研究在青海湖流域冻结期和融化期分别收集了地下水、河水和湖水样品,研究了环青海湖地下水在冻结期和融化期的溶解性碳特征,并探究了不同类型地下水的溶解性碳特征及其对不同冻融时期的响应,最后揭示了环湖区域不同水体的溶解性碳的差异特征及影响因素。结果表明：冻结期地下水、河水和湖水的溶解性无机碳（DIC）均相对高于融化期,溶解性有机碳（DOC）均相对低于融化期。地下水、河水和湖水的溶解性碳均主要以DIC为主,DIC在溶解性碳的占比高达92%。地下水的DIC平均含量在基岩裂隙水、水量中等和浅埋藏的水文地质条件下相对较高,DOC平均含量在基岩裂隙水、水量丰富和浅埋藏的水文地质条件下相对较高。地下水的DIC在湖滨平原砂砾石层、淤泥质砂层潜水和水量中等的水文地质条件下受冻融期影响较大,DOC在基岩裂隙水和水量贫乏的水文地质条件下受冻融期影响较大。湖水的DIC和DOC均远高于河水和地下水。河水的DIC在融化期和冻结期均低于地下水,DOC在融化期高于地下水,在冻结期低于地下水。  相似文献   

夏季长江口南北支溶解有机质的比较     

郭丽霞  王亚松  乔德会  韩露露  郁建春  许云平 《海洋科学》2022,46(11):67-82

本文以2021年5月长江口南北支采集的表层水为研究对象,通过测定氢、氧同位素,溶解有机碳(DOC)浓度,有色溶解有机质(CDOM)的吸收光谱和荧光光谱参数,探讨了夏季长江口北支、南支(北港、北槽、南槽)水体溶解有机质的组成、分布及其影响因素。沿长江下游到河口近海,南、北支DOC浓度分别为1.68±0.16mg/L和1.46±0.31mg/L,CDOM的吸光系数a₃₅₀分别为2.37±0.61m^-1和1.59±0.24m^-1。南支整体具有“高类腐殖质、低类蛋白”的特征,北支则具有“低类腐殖质、低类蛋白”的特征,这可能与南北支的径流量差异有关。在南北支不同分汊河道(北支、南支北港、南支北槽和南支南槽)中,南槽和北支有类似的海水入侵特征,但南槽具有较强的类蛋白组分输入,而南支北港和北槽样品间无显著差异,均表现为河流有机质为主的特征。对比2011年长江南北支DOC和CDOM数据显示,作为长江主河道的南支在2021年无明显变化,而北支有显著的变化。这些结果综合表明长江口DOM的变化格局可能受水动力条件(径流量)、人类活动因素共同作用的影响。比较全球河口DOC和CDOM浓度数据后发现,不同区域的河口具有明显的差异,这可能是因为不同流域在植被覆盖、工农业生产水平、水利工程强度、以及气候变化对土壤侵蚀作用等方面的差异。  相似文献   

Characteristics of bottom dissolved oxygen in Long Island Sound,New York     

Younjoo J. Lee  Kamazima M.M. Lwiza 《Estuarine, Coastal and Shelf Science》2008

The variability of bottom dissolved oxygen (DO) in Long Island Sound, New York, is examined using water quality monitoring data collected by the Connecticut Department of Environmental Protection from 1995 to 2004. Self-organizing map analysis indicates that hypoxia always occurs in the Narrows during summer and less frequently in the Western and the Central Basins. The primary factor controlling the bottom DO, changes spatially and temporally. For non-summer seasons, the levels of bottom DO are strongly associated with water temperature, which means DO availability is primarily driven by solubility. During summer, stratification intensifies under weak wind conditions and bottom DO starts to decrease and deviate from the saturation level except for stations in the Eastern Basin. For the westernmost and shallow (<15 m) stations, bottom DO is correlated with the density stratification (represented by difference between surface and bottom density). In contrast, at deep stations (>20 m), the relationship between oxygen depletion and stratification is not significant. For stations located west of the Central Basin, bottom DO continues to decrease during summer until it reaches its minimum when bottom temperature is around 19–20 °C. In most cases the recovery to saturation levels at the beginning of fall is fast, but not necessarily associated with increased wind mixing. Therefore, we propose that the DO recovery may be a manifestation of either the reduced microbial activity combined with the depletion of organic matter or horizontal exchange. Hypoxic volume is weakly correlated to the summer wind speed, spring total nitrogen, spring chlorophyll a, and maximum river discharge. When all variables are combined in a multiple regression, the coefficient of determination (r²) is 0.92. Surprisingly, the weakest variable is the total nitrogen, because when it is excluded the coefficient r² only drops to 0.84. Spring bloom seems to be an important source of organic carbon pool and biological uptake of oxygen plays a more crucial role in the seasonal evolution of bottom DO than previously thought. Our results indicate that the reassessment phase of the Long Island Sound Total Maximum Daily Load policy on nitrogen loading will most likely fail, because it ignores the contributions of the spring organic carbon pool and river discharge. Also, it is questionable whether the goal of 58.5% anthropogenic nitrogen load reduction is enough.  相似文献   

改性水玻璃砂CO_2硬化工艺性能的研究     

许进 《广东海洋大学学报》2008,28(4)

研究了改性水玻璃砂的基本工艺性能,结果表明:在相同的粘结剂加入量条件下,用不同原砂所得到的型砂抗压强度大小顺序为大林砂>都昌砂>新会砂>岳阳砂;改性水玻璃18#的表面安定性最好,粘结剂加入量增多,表面安定性改善,吹气时间延长,表面安定性恶化;改性水玻璃的抗吸湿性比普通水玻璃好,尤其是改性水玻璃18#的抗吸湿性比普通水玻璃高出一倍以上,随着吹气时间的延长,抗吸湿性提高;改性水玻璃18#、A1和B2的可使用时间均满足生产要求;改性水玻璃B2的发气量最大,18#、A1的发气量略小于普通水玻璃。  相似文献   

Continuous fluorescence assessment of organic matter variability on the Bournbrook River,Birmingham, UK     

Elfrida M. Carstea  Andy Baker  Gabriela Pavelescu  Ian Boomer 《水文研究》2009,23(13):1937-1946

Continuous monitoring of dissolved organic matter (DOM) character and concentration at hourly resolution is rare, despite the importance of analysing organic matter variability at high‐temporal resolution to evaluate river carbon budgeting, river water health by detecting episodic pollution and to determine short‐term variations in chemical and ecological function. The authors report a 2‐week experiment performed on DOM sampled from Bournbrook, Birmingham, UK, an urban river for which spectrophotometric (fluorescence, absorbance), physiochemical (dissolved organic carbon [DOC], electrical conductivity, pH) and isotopic (D/H) parameters have been measured at hourly frequency. Our results show that the river had sub‐daily variations in both organic matter concentration and characteristics. In particular, after relatively high‐magnitude precipitation events, organic carbon concentration increased, with an associated increase in intensity of both humic‐like and tryptophan‐like fluorescence. D/H isotopic ratio demonstrates different hydrological responses to different rainfall events, and organic matter character reflects this difference. Events with precipitation < 2 mm typically yielded isotopically heavy water with relatively hydrophilic DOM and relatively low specific absorbance. Events with precipitation > 2 mm had isotopically lighter water with higher specific absorbance and a decrease in the proportion of microbially derived to humic‐like fluorescence. In our heavily urbanized catchment, we interpret these signals as one where riverine DOM is dominated by storm sewer‐derived ‘old’ organic matter at low‐rainfall amounts and a mixed signal at high‐precipitation amounts where ‘event’ surface runoff‐derived organic matter dominate during storm sewer and combined sewer overflow routed DOM. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

A VERTICAL DISTRIBUTION MODEL OF NUTRIENTS AND DISSOLVED OXYGEN IN THE SOUTHERN TAIWAN STRAIT   总被引：3，自引：0，他引：3  

商少凌  洪华生 《中国海洋湖沼学报》1995,13(1):51-61

Sinoe vertical transport of nutrients and dissolved oxygen are quite important in the water col-umn and have drawn serious attention these recent years, a one-dmension numerical model is tried to simulate the vertical distribution of nutrients and dissolved oxygen in June at two research sites in the southemTaiwan Strait. Physical transport parameters are calibrated by temperature simulation, and thenare used to simulate the profiles of NO_3, PO_4 and dissolved oxygen. The simulation was generally success-ful for both stations. The importance of various factors, such as upwelling tidal current andbiogeochemical activities, which influence the vertical distribution of nutrients and dissolved oxygen, is revealed by analysis of the modeling results. Some important rates, fluxes and ratios are also estimated anddiscussed on the basis of simulation.  相似文献   

Variations in dissolved CO2 and CH4 in a first‐order stream and catchment: an investigation of soil–stream linkages     

Diane Hope  Sheila M. Palmer  Michael F. Billett  Julian J. C. Dawson 《水文研究》2004,18(17):3255-3275

Spatial and seasonal variations in CO₂ and CH₄ concentrations in streamwater and adjacent soils were studied at three sites on Brocky Burn, a headwater stream draining a peatland catchment in upland Britain. Concentrations of both gases in the soil atmosphere were significantly higher in peat and riparian soils than in mineral soils. Peat and riparian soil CO₂ concentrations varied seasonally, showing a positive correlation with air and soil temperature. Streamwater CO₂ concentrations at the upper sampling site, which mostly drained deep peats, varied from 2·8 to 9·8 mg l^?1 (2·5 to 11·9 times atmospheric saturation) and decreased markedly downstream. Temperature‐related seasonal variations in peat and riparian soil CO₂ were reflected in the stream at the upper site, where 77% of biweekly variation was explained by an autoregressive model based on: (i) a negative log‐linear relationship with stream flow; (ii) a positive linear relationship with soil CO₂ concentrations in the shallow riparian wells; and (iii) a negative linear relationship with soil CO₂ concentrations in the shallow peat wells, with a significant 2‐week lag term. These relationships changed markedly downstream, with an apparent decrease in the soil–stream linkage and a switch to a positive relationship between stream flow and stream CO₂. Streamwater CH₄ concentrations also declined sharply downstream, but were much lower (<0·01 to 0·12 mg l^?1) than those of CO₂ and showed no seasonal variation, nor any relationship with soil atmospheric CH₄ concentrations. However, stream CH₄ was significantly correlated with stream flow at the upper site, which explained 57% of biweekly variations in dissolved concentrations. We conclude that stream CO₂ can be a useful integrative measure of whole catchment respiration, but only at sites where the soil–stream linkage is strong. Copyright © 2004 John Wiley & Sons, Ltd.  相似文献